89764-38-5

Basic information

• Product Name: (1R,2S,3S,4S)-2-Methyl-3-(toluene-4-sulfinyl)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester
• CAS NO: 89764-38-5
• Molecular Weight: 318.437
• Mol File: 89764-38-5.mol

Chemical Properties

• CAS DataBase Reference: (1R,2S,3S,4S)-2-Methyl-3-(toluene-4-sulfinyl)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,3S,4S)-2-Methyl-3-(toluene-4-sulfinyl)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester(89764-38-5)
• EPA Substance Registry System: (1R,2S,3S,4S)-2-Methyl-3-(toluene-4-sulfinyl)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester(89764-38-5)

Safety Data

• Hazardous Substances Data: 89764-38-5(Hazardous Substances Data)

Upstream product

• 89764-36-3 E-(R)_S-ethyl p-tolylsulfinylmethylenepropionate 
• 542-92-7 cyclopenta-1,3-diene 

Downstream Products

• 108653-79-8 (-)-(1S,4R)-endo-2-methyl-3-oxobicyclo<2.2.1>heptane-exo-2-carboxaldehyde 
• 89826-18-6 ethyl (+)-(1S,4R)-endo-2-methyl-3-(p-tolylthio)bicyclo<2.2.1>heptane-exo-2-carboxylate 
• 108692-16-6 ethyl (-)-(1R,4S)-exo-2-methyl-endo-3-(p-tlylthio)bicyclo<2.2.1>heptane-endo-2-carboxylate 

Relevant articles and documents

HIGHLY DIASTEREOSELECTIVE DIELS-ALDER REACTION OF OPTICALLY ACTIVE ETHYL 2-p-TOLYLSULFINYLMETHYLENEPROPIONATE WITH CYCLOPENTADIENE

Stereochemistry of the Diels-Alder reaction of ethyl Z- and E-2-p-tolylsulfinylmethylenepropionate with cyclopentadiene has been studied.The high diastereoselectivity was observed especially in the case of exo-cycloaddition.