89768-14-9Relevant articles and documents
Electrolysis in the presence of ultrasound: Cell geometries for the application of extreme rates of mass transfer in electrosynthesis
Marken, Frank,Compton, Richard G.,Davies, Stephen G.,Bull, Steven D.,Thiemann, Thies,Sa E Melo, M. Luisa,Neves, Andre Campos,Castillo, Jose,Jung, C. Gisele,Fontana, Andre
, p. 2055 - 2059 (1997)
Two types of sonoelectrochemical reactors for preparative synthetic work are suggested and characterized by their performance in the reversible one electron reduction of cobalticenium cations in acetonitrile solution. The dominant effect of ultrasound is
Photoinduced electron-transfer systems consisting of electron-donating pyrenes or anthracenes and benzimidazolines for reductive transformation of carbonyl compounds
Hasegawa, Eietsu,Takizawa, Shinya,Seida, Takayuki,Yamaguchi, Akira,Yamaguchi, Naoto,Chiba, Naoki,Takahashi, Tomoya,Ikeda, Hiroshi,Akiyama, Kimio
, p. 6581 - 6588 (2007/10/03)
Photoinduced electron-transfer reactions of several ketone substrates were studied to evaluate the utilities of 1,6-bis(dimethylamino)pyrene (BDMAP), 1,6-dimethoxypyrene (DMP), 9,10-bis(dimethylamino)anthracene (BDMAA), and 9,10-dimethoxyanthracene (DMA) as electron-donating sensitizers cooperating with 2-aryl-1,3-dimethylbenzimidazolines. BDMAP and DMP generally led higher conversion of ketones and better yield of reduction products compared to BDMAA and DMA.
1,3-Dimethyl-2-phenylbenzimidazoline (DMPBI)-acetic acid: An effective reagent system for photoinduced reductive transformation of α,β-epoxy ketones to β-hydroxy ketones
Hasegawa,Chiba,Nakajima,Suzuki,Yoneoka,Iwaya
, p. 1248 - 1252 (2007/10/03)
A combination of 1,3-dimethyl-2-phenylbenzimidazoline (DMPBI) and acetic acid has been utilized for photoinduced reductive transformation of α,β-epoxy ketones to β-hydroxy ketones. Study on photoreactions using several proton donors revealed that acetic acid is superior to other proton donors such as HCl, p-TsOH, MeOH, and water. 1,3-Dimethyl-2-phenylbenzimidazolium was produced in the reaction with acetic acid while N-benzoyl-N,N′-dimethyl-o-phenylenediamine was formed in aqueous solvents. When THF solutions containing aryl carbonyl possessing α,β-epoxy ketones and DMPBI and acetic acid were irradiated (λ > 280 nm), β-hydroxy ketones were isolated in good to excellent yields. Photosensitized conditions (λ > 340 nm) were employed for the reactions of alkyl carbonyl possessing α,β-epoxy ketones.
