897927-89-8Relevant academic research and scientific papers
Synthesis of precursors of gem-difluorodiols and amino alcohols using electrochemical and photochemical reactions
Murakami, Satoru,Fuchigami, Toshio
, p. 1015 - 1020 (2006)
Photo-initiated S-CF2 bond cleavage of electrochemically prepared 4-[difluoro(phenylthio)methyl]-1,3-dioxolanone and 4- [difluoro(phenylthio)methyl]-1,3-oxazolidinone in the presence of olefins provided the corresponding radical addition products, while the photolysis in the presence of aromatics and heteroaromatics provided radical substitution products in moderate yields. Georg Thieme Verlag Stuttgart.
Photochemical generation of difluoromethyl radicals having various functional groups and their highly regioselective addition to olefins and aromatic substitution
Nagura, Hirokatsu,Murakami, Satoru,Fuchigami, Toshio
, p. 10237 - 10245 (2008/02/13)
Difluoromethyl radicals bearing ester, phosphonate, nitrile, cyclic carbonate, and carbamate groups were generated by the photoinitiated S-CF2 bond cleavage of electrosynthesized α,α-difluorosulfides, and their addition to olefins and aromatic substitution were successfully carried out to provide the regioselective adducts and substitution products in moderate yields. The yields of substitution products increased by the addition of diphenyl diselenide and 2,4,6-trimethylpyridine.
