89794-36-5Relevant academic research and scientific papers
A novel hydrogen transfer hydroalumination of alkenes with triisobutylaluminum catalyzed by Pd and other late transition metal complexes
Gagneur, Sebastien,Makabe, Hidefumi,Negishi, Ei-Ichi
, p. 785 - 787 (2007/10/03)
Hydrogen transfer hydroalumination of terminal alkenes and dienes can be achieved with 1.1 equiv. of (i-Bu)3Al and catalytic amounts of Cl2Pd(PPh3)2 and other late transition metal complexes containing Co, Rh, Ni, and Pt at ambient temperature in high yields.
EVOLUTION THERMIQUE DE N-OXYDES DE DIMETHYLAMINO-5 ALCANOLS-1 SUBSTITUES EN 5. COMPETITION ENTRE REARRANGEMENTS DE COPE ET DE MEISENHEIMER
Barbry, Didier,Hasiak, Bruno,Augait, Jean-Michel,Couturier, Daniel
, p. 956 - 961 (2007/10/02)
The effect of the substituent R in the 5 position was studied in the decomposition of 1,5-aminoalcohol N-oxides: Meisenheimer rearrangements takes place when R is the vinyl group but is not observed with the phenyl substituent; elimination to alkenol only
