89805-86-7Relevant academic research and scientific papers
SYNTHESIS AND THERMAL REACTIONS OF 2-ALKYL(OR ARYL)-1-BENZOYL-3,4-DIHYDRO-2-THIANAPHTHALENES
Hori, Mikio,Kataoka, Tadashi,Shimizu, Hiroshi,Tomoto, Akihiko
, p. 3629 - 3632 (2007/10/02)
1-Benzoyl-2-methyl-3,4-dihydro-2-thianaphthalene (4a) underwent novel intermolecular 1,4-rearrangement in refluxing toluene to give an enol ether 5a, while rearrangement of 2-phenyl derivative 4e proceeded intramolecularly in refluxing xylene to afford a 1,4-rearranged enol ether 5b.On the other hand, ylides 4a-e were refluxed in alcohols to afford some ring-opened products 10-12.
