89811-38-1Relevant academic research and scientific papers
REACTION OF AMINONITRENES WITH AZO COMPOUNDS. III. MECHANISM OF THE REACTION OF PHTHALIMIDONITRENE WITH E-ALKYLAZOBENZENES
Suvorov, A. A.,Kuznetsov, M. A.
, p. 1950 - 1954 (2007/10/02)
The addition of phthalimidonitrene to E-alkylazobenzenes RN=NPh takes place stereospecifically with retention of the configuration of the azo group and the formation of 1Z,2Z-2-alkyl-3-phenyl-1-phthalimidoazimines, which are usually unstable and are rapidly converted into equilibrium mixtures of stereoisomers with a preponderance of the 1Z,2E-azimines.
