89813-69-4Relevant academic research and scientific papers
Catalytic enantioselective one-pot approach to cis- and trans-2,3-diaryl substituted 1,5-benzothiazepines
Meninno, Sara,Quaratesi, Ilaria,Volpe, Chiara,Mazzanti, Andrea,Lattanzi, Alessandra
, p. 6923 - 6934 (2018/10/17)
The first enantioselective catalytic approach to cis- and trans-2,3-diaryl substituted 1,5-benzothiazepines has been conveniently developed in a one-pot fashion, starting from α,β-unsaturated acyl pyrazoles and 2-aminothiophenol. The organocatalytic two-s
Multifunctional Photoadditions of Stilbene to Derivatives of Caffeine and Benzothiazole
Kaupp, Gerd,Ringer, Ernst
, p. 1525 - 1539 (2007/10/02)
Electronically excited stilbene (1*) is trapped by 8-substituted caffeine derivatives (2a-f) or 2-chloro- (14) and 2-aminobenzothiazole (21) with variable results.While the electron-rich systems (2c,d) produce mostly propellanes, the halogeno compounds 2a,b and 14 react predominantly via insertion into the C-halogen bond.With 14 there occurs also some C-S insertion, with 21 only N-H insertion.Numerous succeeding reactions are elucidated and the reaction mechanisms discussed.Stilbene (1) photoadds hydrogen chloride to yield 16.
