89822-51-5Relevant academic research and scientific papers
AN EFFICIENT ROUTE TO HETEROARENE-SUBSTITUTED VINYL- AND ALLYL-SILANES VIA PALLADIUM-PHOSPHINE COMPLEX CATALYZED CROSS-COUPLING
Minato, Akio,Suzuki, Keizo
, p. 83 - 86 (2007/10/02)
Heteroarene-substituted vinyl- and allyl-silanes were obtained in good yields by the cross-coupling reaction of either heteroaryl Grignard reagents with halovinyl- and haloallyl-silanes or, alternatively, silyl- and silylmethyl-substituted vinylmetallic reagents with heteroaryl halides in the presence of PdCl2(dppb) as a catalyst.
