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Stereoselective Addition Reaction of Allylic Sulfides to Acetylenic Esters: E/Z Stereochemical Variations by Lewis Acid
Hayakawa, Kenji,Kamikawaji, Yoshimasa,Wakita, Akemi,Kanematsu, Ken
, p. 1985 - 1989 (2007/10/02)
The Lewis acid catalyzed addition reactions of allylic sulfides to methyl propiolate (MP) and dimethyl acetylenedicarboxylate (DMAD) have been investigated.The stereochemical outcome is considerably influenced by the Lewis acid.While the AlCl3-catalyzed r
