899420-61-2Relevant academic research and scientific papers
Redox activation of a B-H bond: A new route to metallaboratrane complexes
Blagg, Robin J.,Charmant, Jonathan P. H.,Connelly, Neil G.,Haddow, Mairi F.,Orpen, A. Guy
, p. 2350 - 2352 (2006)
Oxidative activation of a B-H bond of a coordinated scorpionate ligand provides an unprecedented route to rhodaboratranes. The Royal Society of Chemistry 2006.
A novel route to rhodaboratranes [Rh(CO)(PR3){B(taz) 3}]+via the redox activation of scorpionate complexes [RhLL′Tt]
Blagg, Robin J.,Adams, Christopher J.,Charmant, Jonathan P. H.,Connelly, Neil G.,Haddow, Mairi F.,Hamilton, Alex,Knight, James,Orpen, A. Guy,Ridgway, Benjamin M.
, p. 8724 - 8736 (2011/01/06)
The reaction of a mixture of the sodium salts of dihydrobis(4-ethyl-3- methyl-5-thioxo-1,2,4-triazolyl)borate, NaBt, and hydrotris(4-ethyl-3-methyl-5- thioxo-1,2,4-triazolyl)borate, NaTt, with [{Rh(cod)(μ-Cl)}2] gave [Rh(cod)Bt] and [Rh(cod)Tt]
