89951-99-5Relevant academic research and scientific papers
SYNTHESIS OF A HIGHLY FUNCTIONALISED BICYCLOOCTANE
Hewson, Alan T.,MacPerson, David T.
, p. 5807 - 5808 (1983)
The bicyclooctanes 4 and 5 are prepared by making use of vinyl phosphonium salts, and 4 is used in formal total syntheses of chrysomelidial and loganin.
Total Synthesis of Cyclopentanoid Natural Products
Hewson, Alan T.,MacPherson, David T.
, p. 2625 - 2636 (2007/10/02)
The highly functionalised bicyclooctanes (5) and (6) have been prepared by a sequence involving intramolecular Wittig reactions of the diketo ester (9) with vinyl phosphonium salts (3) and (4).Compounds (5) and (6) have then been used as starting m
