89952-16-9

Basic information

• Product Name: [Pd(CNC₆H₃-2,6-Me₂)2((CN)2CC(CF₃)2)]
• CAS NO: 89952-16-9
• Molecular Weight: 582.844
• Mol File: 89952-16-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(CNC₆H₃-2,6-Me₂)2((CN)2CC(CF₃)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(CNC₆H₃-2,6-Me₂)2((CN)2CC(CF₃)2)](89952-16-9)
• EPA Substance Registry System: [Pd(CNC₆H₃-2,6-Me₂)2((CN)2CC(CF₃)2)](89952-16-9)

Safety Data

• Hazardous Substances Data: 89952-16-9(Hazardous Substances Data)

Upstream product

• 89668-96-2 Pd₃(2,6-dimethylphenyl isocyanide)6 
• 1113-69-5 1,1-dicyano-2,2-bis(trifluoromethyl)ethene 

Relevant articles and documents

XYLYL ISOCYANIDE PLATINUM AND PALLADIUM COMPLEXES

Bis(cycloocta-1,5-diene)platinum reacts with isopropyl isocyanide to give the trinuclear complex .A related palladium compound was prepared by treating either or with 2,6-dimethylphenyl isocyanide.Reactions of the cluster and its presumed palladium analogue with the olefins (NC)2C:C(CN)2, F2C:CFCl and (CN)2C:C(CF3)2, give the compounds (M=Pt, Pd) in which the metals are η2-bonded to the coordinated olefins.The compound reacts with F2C:CFBr and with F2C:CFCl to give the traans complexes (X=Br, Cl).Similar compounds (M=Pt, Pd), (L=MeO2CHC:CHCO2Me, OCH:CHCO) have also been prepared, and characterised.Two platinum complexes 2> and (CNC6H3-2,6-Me2)4> have been synthesized by treating the complex with HSiMePh2 and cyclopropenone, respectively.NMR and IR data for the new species are reported and discussed.