89954-92-7

Upstream product

• 829-84-5 dicyclohexylphosphane 

Downstream Products

• 91886-01-0 HgClBr(HP(C₆H₁₁)2)2 
• 91886-03-2 HgBrI(HP(C₆H₁₁)2)2 
• 91885-99-3 HgBr₂(HP(C₆H₁₁)2)3 
• 91885-73-3 HgBr₂((C₆H₁₁)2PC(S)N(H)C₆H₅)2 
• 91885-84-6 HgBr₂((C₆H₁₁)2PH)((C₆H₁₁)2PC(S)N(H)C₆H₅) 

Relevant academic research and scientific papers

On the Reaction of Mercury(II) Halides with Secondary Phosphanes

Mercury(II) halides form coordination compounds (X = Cl, Br, I; R = tBu, cyclohexyl; n = 1, 2).Deprotonation of these complexes with Et3N yields phosphinomercury compounds XHgPR2 which are also accessible from HgX2 and LiPR2 or Hg(PR2)2 (R = tBu) and HgX2.IHgPCy2 coordinates I- leading to anionic complexes with an eight-membered (Hg - P)4 ring structure.The first reported 2J(199Hg, 199Hg) coupling constant amount between 2435 and 2959 Hz in these rings.