899793-78-3Relevant articles and documents
An effective strategy to tune supramolecular interaction via a spiro-bridged spacer in oligothiophene-S,S-dioxides and their anomalous photoluminescent behavior
Xie, Ling-Hai,Hou, Xiao-Ya,Hua, Yu-Ran,Huang, Yan-Qin,Zhao, Bao-Min,Liu, Feng,Peng, Bo,Wei, Wei,Huang, Wei
, p. 1619 - 1622 (2008/02/02)
We demonstrate that incorporating nonplanar spiro-bridged structures is an effective strategy for tuning supramolecular interactions of optoelectronic functional moieties. In the model compounds spiro-bridged oligothiophene-S,S- dioxides (BSiSDTFO), unusual dimers constructed by spiro-bridged spacers do not form excimers, which is confirmed by crystallographic data and fluorescent emission spectra.