89982-27-4Relevant academic research and scientific papers
Phosphorus azides, powerful reagents in heterocyclic chemistry
Majoral, Jean-Pierre,Bertrand, Guy,Ocando-Mavarez, Edgar,Baceiredo, Antoine
, p. 945 - 958 (2007/10/02)
The Curtius type rearrangement is effective for tetracoordinated and pentacoordinated phosphorus azides.Competitive nitrene-type reactions sometimes occur.On the other hand, irradionation of tricoordinated phosphorus azides lead to the generation of phosp
PHOTOLYSIS OF PHOSPHONIUMS AND PHOSPHORANES AZIDES
Majoral, J. P.,Bertrand, G.,Baceiredo, A.,Mulliez, M.,Schmutzler, R.
, p. 221 - 224 (2007/10/02)
First evidence for a Curtius type rearrangement involving a pentacoordinated atom and charged species are described.
