899822-68-5

Basic information

• Product Name: (S_S)-5-methoxy-2-methyl-3-(toluene-4-sulfinyl)-[1,4]benzoquinone
• Synonyms: (S_S)-5-methoxy-2-methyl-3-(toluene-4-sulfinyl)-[1,4]benzoquinone
• CAS NO: 899822-68-5
• Molecular Weight: 290.34
• Mol File: 899822-68-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S_S)-5-methoxy-2-methyl-3-(toluene-4-sulfinyl)-[1,4]benzoquinone(CAS DataBase Reference)
• NIST Chemistry Reference: (S_S)-5-methoxy-2-methyl-3-(toluene-4-sulfinyl)-[1,4]benzoquinone(899822-68-5)
• EPA Substance Registry System: (S_S)-5-methoxy-2-methyl-3-(toluene-4-sulfinyl)-[1,4]benzoquinone(899822-68-5)

Safety Data

• Hazardous Substances Data: 899822-68-5(Hazardous Substances Data)

Upstream product

• 74516-54-4 2-hydroxy-4-methyl-5-methoxybenzaldehyde 
• 899822-84-5 formic acid 3-bromo-2,5-dimethoxy-4-methylphenyl ester 
• 899822-73-2 1-bromo-2,5-dimethoxy-3-hydroxy-6-methylbenzene 
• 899822-71-0 3-bromo-2-hydroxy-5-methoxy-4-methylbenzaldehyde 
• 899822-74-3 3-bromo-1,2,5-trimethoxy-4-methylbenzene 
• 899822-72-1 3-bromo-2,5-dimethoxy-4-methylbenzaldehyde 
• 899822-75-4 (S_S)-1,2,5-trimethoxy-4-methyl-3-(toluene-4-sulfinyl)benzene 

Downstream Products

• 1310817-47-0 (2R,6aS,10aR,10bS)-10a-[(S)-(toluene-4-sulfinyl)]-9-methoxy-6a-methyl-2-phenyl-6,6a,10a,10b-tetrahydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-46-9 (2S,6aS,10aR,10bS)-10a-[(S)-(toluene-4-sulfinyl)]-9-methoxy-6a-methyl-2-phenyl-6,6a,10a,10b-tetrahydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-30-1 C₂₅H₂₄O₆S 
• 1310817-50-5 2-(2,5-dimethoxy-4-methylphenyl)-9-methoxy-6a-methyl-10a-[(S)-(toluene-4-sulfinyl)]-6,6a,10a,10b-tetrahydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-49-2 (2R,6aS,10aR,10bS)-2-(furan-2-yl)-9-methoxy-6a-methyl-10a-[(S)-(toluene-4-sulfinyl)]-6,6a,10a,10b-tetrahydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-48-1 (2S,6aS,10aR,10bS)-2-(furan-2-yl)-9-methoxy-6a-methyl-10a-[(S)-(toluene-4-sulfinyl)]-6,6a,10a,10b-tetrahydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-44-7 (2S,6aS,10aR,10bS)-2-(furan-3-yl)-9-methoxy-6a-methyl-10a-[(S)-(toluene-4-sulfinyl)]-6,6a,10a,10b-tetrahydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-61-8 C₂₇H₂₈O₆S 
• 1310817-29-8 (4aR,4bS,10aS)-3-methoxy-10a-methyl-4a-[(S)-(toluene-4-sulfinyl)]-4a,4b,5,6,7,8,10,10a-octahydrophenanthrene-1,4-dione 
• 1310817-45-8 (2R,6aS,10aR,10bS)-2-(furan-3-yl)-9-methoxy-6a-methyl-10a-[(S)-(toluene-4-sulfinyl)]-6,6a,10a,10b-tetrahydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-58-3 (2S,6aR)-9-methoxy-6a-methyl-2-phenyl-6,6a-dihydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-59-4 (2R,6aR)-9-methoxy-6a-methyl-2-phenyl-6,6a-dihydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-53-8 (+)-(2S,6aR,10aR,10bR)-9-methoxy-6a-methyl-2-phenyl-6,6a,10a,10b-tetrahydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 
• 1310817-54-9 (-)-(2R,6aR,10aR,10bR)-9-methoxy-6a-methyl-2-phenyl-6,6a,10a,10b-tetrahydro-1H-benzo[f]isochromene-7,10(2H,4H)-dione 

Relevant articles and documents

Asymmetric Diels-Alder reactions of a new enantiomerically pure sulfinylquinone: A straightforward access to functionalized Wieland-Miescher ketone analogues with (R) absolute configuration

An efficient and highly stereocontrolled preparation, on a large scale, of two new Wieland-Miescher-type diketones is described. The approach centers on a diastereoselective Diels-Alder reaction using a new enantiomerically pure sulfinylquinone. Mechanist