90020-49-8Relevant academic research and scientific papers
Preparation of Vinylic Sulphones by Peterson Olefination using Phenyl Trimethylsilylmethyl Sulphone
Craig, Donald,Ley, Steven V.,Simpkins, Nigel S.,Whitham, Gordon H.,Prior, Michael J.
, p. 1949 - 1952 (2007/10/02)
The anion generated from phenyl trimethylsilylmethyl sulphone using butyl-lithium in dimethoxyethane, readily reacts at -78 deg C with various carbonyl compounds to afford vinylic sulphones on work-up at room temperature.The reaction conditions are tolera
Peterson Olefination using Phenylsulphonyltrimethylsilylmethane. A New Preparation of Vinylic Sulphones
Ley, Steven V.,Simpkins, Nigel S.
, p. 1281 - 1282 (2007/10/02)
The anion from phenylsulphonyltrimethylsilylmethane reacts, in 1,2-dimethoxyethane at -78 deg C, with both aldehydes and ketones to give the corresponding alkenyl phenyl sulphones in good yield.
