90022-80-3

Upstream product

• 1013-88-3 Benzophenone imine 
• 14040-11-0 tungsten hexacarbonyl 
• 368-39-8 triethyloxonium fluoroborate 
• 627-48-5 ethyl cyanate 

Downstream Products

• 99143-36-9 {(CO)5W(CNC(C₆H₅)2)}2 
• 104155-40-0 (CO)5WCNC(C₆H₅)2⁽¹⁺⁾*BF₄^(1-)=(CO)5WCNC(C₆H₅)2BF₄ 

Relevant academic research and scientific papers

1-ALKOXY-2-AZAALLENYL-KOMPLEXE VON CHROM UND WOLFRAM

The successive reaction of (CO)6M with Na12> and BF4 yields (CO)5M12)OEt> (II: M = Cr; III: M = W; CR12 = C(C6H4Br-p)2 (a),CPh2 (b), C(C6H4OMe-p)2 (c), C(C6H4)2O (d), CBut2 (e)).Hexacarbonyltungsten, (CO)6W, reacts with Na and MeOSO2F to give (CO)5W (IV).X-Ray analysis of IIe shows that: (1) the C=N=C fragmentis almost linear (171.7 deg); (2) the two N=C bond lengths are equal within experimental error; and (3) the O,C,CrN plane is perpendicular to the C(Me3),C,N,(Me3) plane (90.0 deg).Therefore compounds II-IV are best described as 1-alkoxy-2-azaallenyl complexes.

-UND -PENTACARBONYLWOLFRAM-KOMPLEXE DURCH INSERTION VON RXCN (X=O, S) IN DIE WOLFRAM-CARBENKOHLENSTOFF-BINDUNG

Pentacarbonyl(diphenylcarbene)tungsten reacts with organyl cyanates, ROCN (R = Ph, Et, Pri), or alkyl thiocyanates, R'SCN (R' = Me, Et, Pri), respectively, inserting the CN group into the tungsten-carbene bond to give pentacarb