90027-02-4 Usage
Structure
Bicyclic, containing a triazine ring and an azabenzene ring
Ligands
Can bind to metal catalysts, particularly palladium and platinum
Use in organic synthesis
Selective hydrogenation of unsaturated compounds
Affinity for metals
High affinity for metals such as palladium and platinum
Potential applications
Organic light-emitting diodes (OLEDs), chiral auxiliary in asymmetric synthesis, and various chemical and materials science applications.
Check Digit Verification of cas no
The CAS Registry Mumber 90027-02-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,0,0,2 and 7 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 90027-02:
(7*9)+(6*0)+(5*0)+(4*2)+(3*7)+(2*0)+(1*2)=94
94 % 10 = 4
So 90027-02-4 is a valid CAS Registry Number.
90027-02-4Relevant articles and documents
STEREOSPECIFITY OF 3JCH SPIN-SPIN COUPLING CONSTANTS IN BICYCLIC cis-DIAZIRINES: STEREOCHEMISTRY OF 2,4,6-TRIALKYL-1,3,5-TRIAZABICYCLOHEXANES
Denisenko, S. N.,Shustov, G. V.,Chervin, I. I.,Kostyanovskii, R. G.
, p. 1104 - 1109 (2007/10/02)
Stereospecifity of 3JC,N,C,H spin-spin coupling constants (3Jtrans > Jgauche) in the 13C NMR spectra of 1,5-diaza- and 1,3,5-triazabicyclohexanes was observed.Proceeding from this, the preferred conformations of the d,l and meso isomers of 2,4,6-trialkyl-1,3,5-triazabicyclohexanes were established, and a mechanism for the interconversion of these isomers via openings of the five-membered ring ans imino-enamine equilibrium was proposed.It is also shown, that the stereochemical result of the Schmitz reaction is determined in the step involving cyclization of the iminium intermediate.
