90029-47-3Relevant academic research and scientific papers
Some reactions of tris(2,2,2-trifluoroethyl) phosphite: A new ligand for organometallic chemistry
Shreeve, Jean'ne M.,Williamson, Stanley M.
, p. 1104 - 1107 (2008/10/08)
The reactions of P(OCH2CF3)3 with three different types of metallocarbonyl compounds Ni(CO)4, (η5-C5H5)Fe(CO)2I, and (η6-1,3,5-(CH3)3C6H 3)Cr(CO)3 cleanly form products derived from displacement of CO. The products (CO)Ni(P(OCH2CF3)3)3, (CO)2Ni(P(OCH2CF3)3)2, (η5-C5H5)FeI(P(OCH2CF 3)3)2, and (η6-1,3,5-(CH3)3C6H 3)Cr(CO)2P(OCH2CF3)3 are obtained in good yields and are relatively stable. Both thermal and photochemical modes of reaction are observed.
