90036-77-4Relevant academic research and scientific papers
Synthesis of 2-Methylene-1,3-dioxygenated Cyclopentanes and Cyclopentenes
Chantarasiri, Nuanphun,Dinprasert, Pranee,Thebtaranonth, Chachanat,Thebtaranonth, Yodhathai,Yenjai, Chavi
, p. 286 - 288 (2007/10/02)
Antracene adducts (4)-(6) are synthesized via a convenient general synthesis and subjected to a retro Diels-Alder reaction to furnish the corresponding 2-methylene-1,3-dioxygenated cyclopentenes and cyclopentanes (1)-(3) via either flash vaccum pyrolysis or room temperature silica gel-catalysed decomposition.
Acid catalysis of the retro-diels alder reaction. Formation and electrophilic reactivity of 2-methylene-1,3-cyclopentanedione.
Bunnelle, William H.,Randall Shangraw
, p. 2005 - 2011 (2007/10/02)
The acid mediated decomposition of the Diels-A1der adduct of 1,3-cyclopentanedione with anthracene was studied. An extremely facile, acid catalyzed retro-Diels-Alder fragmentation produces 2-methylene-1,3-cyclopentanedione, which undergoes twofold electrophilic substitution on the cognate anthracene nucleus.
