90056-29-4

Upstream product

• 90129-47-8 (4S,5R)-4-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone 
• 90056-28-3 (4S,5R)-5-Isopropenyl-2-methyl-4-vinyloxy-cyclohex-2-enone 

Downstream Products

• 90056-30-7 ((1R,4S,6R)-6-Hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-acetaldehyde 
• 119619-15-7 Methyl (1S,3R,6R)-3-(2-acetoxypropyl)-3-methyl-6-(1-methylethenyl)-2-oxo-4-cyclohexene-1-carboxylate 
• 119619-17-9 Methyl (1S,3R,6R)-3-methyl-6-(1-methylethenyl)-2-oxo-3-(2-oxopropyl)-4-cyclohexene-1-carboxylate 
• 119619-14-6 (2R,5S)-2-(2-Acetoxypropyl)-2-methyl-5-(1-methylethenyl)-3-cyclohexen-1-one 
• 119619-13-5 Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester 

Relevant academic research and scientific papers

Stereoselective Total Synthesis of (-)-Picrotoxnin and (-)-Picrotin

The stereoselective total synthesis of (-)-picritoxnin (1) and (-)-picrotin (2), starting from (+)-5β-hydroxycarvone (3), is described.Eight contiguous asymmetric centers on a cis-fused hydrindane ring system were stereoselectively prepared via three key