90084-14-3

Basic information

• Product Name: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-3E-buten-2-one
• Synonyms: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-3E-buten-2-one
• CAS NO: 90084-14-3
• Molecular Weight: 224.343
• Mol File: 90084-14-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-3E-buten-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-3E-buten-2-one(90084-14-3)
• EPA Substance Registry System: 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-3E-buten-2-one(90084-14-3)

Safety Data

• Hazardous Substances Data: 90084-14-3(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 51731-17-0 trans-4-methoxy-3-buten-2-one 

Downstream Products

• 250267-12-0 (1E)3-methyl-1,3-butadiene, [2-isopropyl-5-methylcyclohexyl ether-(1R,2S,5R)] 

Relevant articles and documents

Photooxygenation of chiral dienol ethers: Asymmetric synthesis of alkoxydioxines

The addition of 1O2 to chiral dienol ethers provides a new route to alkoxydioxines (alkoxyendoperoxides). Depending upon substitution and geometry, the [4+2] cycloaddition is accompanied or even supplanted by [2+2] cycloaddition leading to alkene cleavage and/or ene-like reaction leading to allylic hydroperoxides. The diastereoselectivity of cycloaddition is ultimately limited by the conformational freedom of the dienol ether substrates.