90095-27-5Relevant academic research and scientific papers
Topotactic elimination of water across a C-C ligand bond in a dense 3-D metal-organic framework
Yeung, Hamish H.-M.,Kosa, Monica,Griffin, John M.,Grey, Clare P.,Major, Dan T.,Cheetham, Anthony K.
supporting information, p. 13292 - 13295 (2015/05/20)
Upon heating, lithium l-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations. This journal is
Ligand-directed control over crystal structures of inorganic-organic frameworks and formation of solid solutions
Yeung, Hamish H.-M.,Li, Wei,Saines, Paul J.,Koester, Thomas K. J.,Grey, Clare P.,Cheetham, Anthony K.
supporting information, p. 5544 - 5547 (2013/06/27)
Grounded in fact: Inorganic-organic frameworks with 3D Li-O-Li connectivity can form solid solutions through mechanochemical synthesis. High-resolution synchrotron powder X-ray diffraction and cross-polarization solid-state NMR spectroscopy demonstrate co
