90106-96-0Relevant academic research and scientific papers
Silylmethyl Radical Cyclization: New Stereoselective Method for 1,3-Diol Synthesis from Allylic Alcohols
Nishiyama, Hisao,Kitajima, Toshio,Matsumoto, Makoto,Itoh, Kenji
, p. 2298 - 2300 (2007/10/02)
Cyclizations of (bromomethyl)dimethylsilyl allylic ethers by treatment with tri-n-butyltin hydride in a free-radical process followed by oxidation in a one-pot manner with hydrogen peroxide gave th corresponding 1,3-diols predominantly with high stereoselectivity.
