90107-00-9Relevant academic research and scientific papers
A novel approach for the formation of carbon-nitrogen bonds: Azidation of alkyl radicals with sulfonyl azides
Ollivier,Renaud
, p. 4717 - 4727 (2007/10/03)
Two preparatively attractive methods for the azidation of alkyl radicals are described. Secondary and tertiary alkyl iodides and dithiocarbonates are easily converted into the corresponding azides, either by reaction with ethanesulfonyl azide in the prese
Silylmethyl Radical Cyclization: New Stereoselective Method for 1,3-Diol Synthesis from Allylic Alcohols
Nishiyama, Hisao,Kitajima, Toshio,Matsumoto, Makoto,Itoh, Kenji
, p. 2298 - 2300 (2007/10/02)
Cyclizations of (bromomethyl)dimethylsilyl allylic ethers by treatment with tri-n-butyltin hydride in a free-radical process followed by oxidation in a one-pot manner with hydrogen peroxide gave th corresponding 1,3-diols predominantly with high stereoselectivity.
