901126-39-4Relevant academic research and scientific papers
(R)- and (S)-4-TIPS-3-butyn-2-ol. Useful precursors of chiral allenylzinc and indium reagents
Marshall, James A.,Eidam, Patrick,Eidam, Hilary Schenck
, p. 4840 - 4844 (2006)
A convenient route to the enantiomers of 4-TIPS-3-butyn-2-ol of >95% enantiomeric purity by reduction of the ynone precursor 4 with the Noyori N-tosyl-1,2-diphenylethylenediamineruthenium cymene catalyst is described. The mesylate derivative of the (S) en
