90114-67-3

Upstream product

• 14675-51-5 p-nitrophenyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 2873-29-2 D-glucal triacetate 

Downstream Products

• 109455-04-1 (4aR)-6c-(4-nitro-phenoxy)-2-phenyl-(4ar,8at)-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3,2]dioxaborinine 
• 157430-17-6 4-nitrophenyl 6-O-(tert-butyldimethylsilyl)-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 273199-63-6 4-nitrophenyl 6-O-(tert-butyldimethylsilyl)-2,3-dideoxy-α-D-threo-hex-2-enopyranoside 
• 220758-16-7 4-nirtophenyl 4-O-(2'-bromoprop-2'-enyl)-6-O-(tert-butyldimethylsilyl)-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 220758-07-6 4-nitrophenyl 4-O-(2'-bromoprop-2'-enyl)-6-O-(tert-butyldimethylsilyl)-2,3-dideoxy-α-D-threo-hex-2-enopyranoside 

Relevant academic research and scientific papers

Palladium-mediated cyclization on carbohydrate templates. 3. extension of the cyclization to the threo series

The palladium(0)-catalyzed Heck-type cyclization-β-alkoxy elimination reaction leading to enantiopure bicyclic compounds in the case of erythro 2,3-unsaturated glycosides has been successfully extended to the threo stereoisomer by only changing the aglyco

An easy and efficient preparation of aryl α-O-Δ2-glycosides

Ferrier reaction between acetylglycals and p-NO2, m-NO2 and p-t-butylphenol after recrystallization gave aryl O-Δ2-glycosides as the pure α anomers. Deacetylation of these compounds and benzylation of the crude diol led to