90115-54-1Relevant academic research and scientific papers
Aryl Triflates in On-Surface Chemistry
Fuchs, Harald,Gao, Hong-Ying,Klaasen, Henning,Neugebauer, Johannes,Ren, Jindong,Studer, Armido,Viergutz, Lena,Witteler, Melanie C.
, p. 16727 - 16732 (2020)
The reactivity of aryl triflates in on-surface C?C coupling is reported. It is shown that the triflate group in aryl triflates enables regioselective homo coupling with preceding or concomitant hydrodetriflation on Cu(111). Three different symmetrical π-s
Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups
Kundu, Subrata,Miceli, Enrico,Farquhar, Erik R.,Ray, Kallol
, p. 4264 - 4267 (2014/03/21)
Oxidation of phenols by heterodinuclear CuIII(μ-O) 2NiIII complexes containing nucleophilic oxo groups occurs by both proton coupled electron transfer (PCET) and hydrogen atom transfer (HAT) mechanisms; the exact mechanism
Chirality transcription and amplification by [2]pseudorotaxanes
Kuwahara, Shunsuke,Chamura, Rie,Tsuchiya, Sho,Ikeda, Mari,Habata, Yoichi
, p. 2186 - 2188 (2013/04/10)
Chirality transcription and amplification by the formation of chiral [2]pseudorotaxanes by an achiral crown ether having the 2′, 2′′-quaterphenyl group and chiral sec-ammonium ions are reported. It was revealed that the absolute configurations of the chiral sec-ammonium ions can be detected directly from the CD spectra of the chiral [2]pseudorotaxanes.
Tropos deoxycholic acid-derived biphenylphosphites: synthesis, stereochemical characterization and use as chiral ligands in the copper catalyzed conjugate addition of diethylzinc to acyclic enones
Facchetti, Sarah,Losi, Debora,Iuliano, Anna
, p. 2993 - 3003 (2007/10/03)
Three new deoxycholic acid-based 5,5′-substituted biphenylphosphites, 2-4, were synthesized and their stereochemical features were examined by CD and NMR spectroscopy, which allowed us to determine the sense of twist of the substituted biphenyl moiety as
