90123-46-9

Basic information

• Product Name: α-Acetyl-α-(2-cyclopentenyl)acetic acid methyl ester
• Synonyms: 2-(2-Cyclopentenyl)acetoacetic acid methyl ester;α-Acetyl-α-(2-cyclopentenyl)acetic acid methyl ester
• CAS NO: 90123-46-9
• Molecular Formula: C10H14O3
• Molecular Weight: 182.22
• Mol File: 90123-46-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: α-Acetyl-α-(2-cyclopentenyl)acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: α-Acetyl-α-(2-cyclopentenyl)acetic acid methyl ester(90123-46-9)
• EPA Substance Registry System: α-Acetyl-α-(2-cyclopentenyl)acetic acid methyl ester(90123-46-9)

Safety Data

• Hazardous Substances Data: 90123-46-9(Hazardous Substances Data)

Upstream product

• 90123-27-6 methyl-4,4-dimethoxy-2-(2-cyclopentenyl)-butyrate 
• 13668-61-6 (cyclopent-2-eneyl)acetic acid 

Relevant articles and documents

IRIDOIDS: THE TOTAL SYNTHESIS OF THE AGLUCONES OF (+/-)-8-EPILOGANIN AND (+/-)-MUSSAENOSIDE VIA BICYCLOOCTENES

The nitrone-olefin cycloaddition reaction has been used to construct cisfused bicyclooctanes or diquinanes as potential intermediates for C-11 functionalized iridoids.The isoxaolidine 7 was obtained in four steps from the commercially available 2-cyclopentene-1-acetic acid 4.Different functionalized diquinanes 8 to 19 and 22 to 24 have been prepared.As illustrative examples of iridoid synthesis, compounds 21 and 26, the O-methyl protected aglucones of (+/-)-8-epiloganin (2) and (+/-)-mussaenoside (3) have been synthesized starting from the common key-intermediate 11.