90129-40-1Relevant academic research and scientific papers
Synthesis of wasabidienone a via a novel acyl rearrangement reaction from carbon to oxygen
Sato, Shingo,Obara, Heitaro,Yusa, Katsuhiro,Sudo, Kazuhiro,Sando, Masaharu,Kagaya, Hiroyuki,Ijichi, Hiroki,Matsuba, Shigeru,Kumazawa, Toshihiro,Onodera, Jun-Ichi
, p. 889 - 893 (2007/10/03)
Wasabidienone A (WA), a tautomeric mixture of 5-hydroxy-3-methoxy-4,6- dimethyl-(6S)-[(2R)-2-methylbutyryloxy]-cyclohexa-2,4-dien-1-one (1a) and 5- hydroxy-3-methoxy-2,6-dimethyl-(6R)-[(2R)-2-methylbutyryloxy]cyclohexa-2,4- dien-1-one (1b) was synthesized via a novel rearrangement reaction of an acyl group from carbon to the β-hydroxy oxygen on the cyclohexadienone ring. This reaction may occur during fermentation of Phoma wasabiae to form WA from WB1.
