90164-77-5

Basic information

• Product Name: methyl [2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->3)]-4-O-benzyl-α-L-rhamnopyranoside
• Synonyms: methyl [2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->3)]-4-O-benzyl-α-L-rhamnopyranoside
• CAS NO: 90164-77-5
• Molecular Weight: 790.951
• Mol File: 90164-77-5.mol

Chemical Properties

• CAS DataBase Reference: methyl [2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->3)]-4-O-benzyl-α-L-rhamnopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl [2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->3)]-4-O-benzyl-α-L-rhamnopyranoside(90164-77-5)
• EPA Substance Registry System: methyl [2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->3)]-4-O-benzyl-α-L-rhamnopyranoside(90164-77-5)

Safety Data

• Hazardous Substances Data: 90164-77-5(Hazardous Substances Data)

Upstream product

• 71715-59-8 methyl 2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranoside 
• 4196-35-4 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl bromide 
• 67773-43-7 2,3,4,6-tetra-O-benzyl-α/β-D-glucopyranosyl bromide 
• 25019-69-6 methyl 4-O-benzyl-α-L-rhamnopyranoside 

Downstream Products

• 144431-90-3 methyl (2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->3)]-4-O-benzyl-α-L-rhamnopyranoside 
• 247092-75-7 methyl (2-O-acetyl-3,4-di-O-allyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside 
• 1092100-15-6 methyl (3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->3)]-4-O-benzyl-α-L-rhamnopyranoside 
• 247092-77-9 methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-allyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside 
• 247092-79-1 methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside 
• 105213-62-5 methyl (2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside 
• 247092-78-0 methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-α-L-rhamnopyranosyl-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside 
• 247092-76-8 methyl (3,4-di-O-allyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside 
• 247092-66-6 methyl (2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-(1->2)-[α-D-glucopyranosyl-(1->3)]-α-L-rhamnopyranoside 
• 247092-64-4 methyl (2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->3)]-4-O-benzyl-α-L-rhamnopyranoside 

Relevant articles and documents

Synthesis of a tri- and tetrasaccharide fragment specific for the Shigella flexneri serotype 5a O-antigen. A reinvestigation

Stereocontrolled, stepwise synthesis of methyl α-L-rhamnopyranosyl-(1→2)-[α-D-glucopyranosyl-(1→3)]-α-L-rhamnopyranoside (A(E)B, 1) and methyl 2-acetamido-2-deoxy-β-D-glucopyranosyl-(1→2)-α-L-rhamnopyranosyl -(1→2)-[α-D-glucopyranosyl-(1 →3)]-α-L-rhamnopy

Synthesis and (13)C NMR spectra of 2,3-di-O-glycosyl derivatives of methyl α-L-rhamnopyranoside and methyl α-D-mannopyranoside

The syntheses are described of 2,3-di-O-glycosyl derivatives of methyl α-L-rhamnopyranoside (1-5) and α-D-mannopyranoside (6-9). The deviation from additivity in (13)C NMR spectra calculated for 1-9 were similar for stereochemically rela