90172-90-0Relevant academic research and scientific papers
A chemoenzymatic approach to the stereocontrolled synthesis of the C1-C11 fragment of (+)-peloruside A
Schoenherr, Heike,Mollitor, Jan,Schneider, Christoph
experimental part, p. 3908 - 3918 (2010/09/05)
A highly efficient and diastereoselective synthesis of the C1C11 fragment of the marine natural product (+)-peloruside A has been developed. Through enzymatic desymmetrization of diethyl 3-hydroxyglutarate with lipase B from Candida antarctica a large-sca
Vinylogous Wolff Rearrangement. 4. General Reaction of β,γ-Unsaturated α'-Diazo Ketones
Smith, Amos B.,Toder, Bruce H.,Branca, Stephen J.
, p. 3995 - 4001 (2007/10/02)
The preparation and vinylogous Wolff rearrangement (VWR) of some 21 acyclic and monocyclic β,γ-unsaturated α'-diazo ketones are described.The resulting γ,δ-unsaturated esters are summarized in Tables I-VI.The rearrangement is promoted by CuSO4, Cu(AcAc)2,
