902153-27-9Relevant academic research and scientific papers
Synthesis of a rhodaazacyclopropane and characterization of its radical cation by EPR spectroscopy
Maire, Pascal,Sreekanth, Anandaram,Buettner, Torsten,Harmer, Jeffrey,Gromov, Igor,Rueegger, Heinz,Breher, Frank,Schweiger, Arthur,Gruetzmacher, Hansjoerg
, p. 3265 - 3269 (2008/02/11)
(Chemical Equation Presented) Rh steps into the ring: The radical cation shown is best described as a rhodaazacyclopropane (A) rather than as a Rh I iminium ion complex (B). EPR and DFT data indicate that the delocalization of the unpaired electron into the ligand framework contributes to the stability of A (see plot of the singly occupied molecular orbital).
