90255-43-9Relevant academic research and scientific papers
Transition Metal Methylene Complexes, XLV. A Simplified Synthetic Method for μ-Alkylidene Complexes Demonstrated for the Preparation of Novel Dimetallaspiranes
Herrmann, Wolfgang A.,Weber, Cornelia,Ziegler, Manfred L.,Pahl, Claudia
, p. 875 - 894 (2007/10/02)
The organometallic complexes 1a and 1b react at the metal-metal double bond with the hydrazones 2a - i in the presence of manganese dioxide to give, via the corresponding diazoalkane intermediates, the μ-alkylidene complexes 3a - i and 4a - c, f, i, respe
