902779-55-9Relevant academic research and scientific papers
Titanium-salan-catalyzed asymmetric oxidation of sulfides and kinetic resolution of sulfoxides with H2O2 as the oxidant
Bryliakov, Konstantin P.,Talsi, Evgenii P.
, p. 3369 - 3376 (2008)
Asymmetric oxidation of sufides to sulfoxides by aqueous hydrogen peroxide with catalysis by titanium-salan complexes is presented. Optically active sulfoxides have been obtained with good to high enantioselectivities (up to 97% ee) by a tandem enantioselective oxidation and kinetic resolution procedure, the catalyst performing over 500 turnovers with no loss of enantioselectivity. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
