902781-09-3

Basic information

• Product Name: Benzenamine, N,2,6-trimethyl-N-phenyl-
• CAS NO: 902781-09-3
• Molecular Formula: C15H17N
• Molecular Weight: 211.307
• Mol File: 902781-09-3.mol

Chemical Properties

• CAS DataBase Reference: Benzenamine, N,2,6-trimethyl-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N,2,6-trimethyl-N-phenyl-(902781-09-3)
• EPA Substance Registry System: Benzenamine, N,2,6-trimethyl-N-phenyl-(902781-09-3)

Safety Data

• Hazardous Substances Data: 902781-09-3(Hazardous Substances Data)

Upstream product

• 6781-98-2 2,6-dimethyl-1-chlorobenzene 
• 100-61-8 N-methylaniline 

Relevant articles and documents

[Pd(IPr*)(acac)CI]: An easily synthesized, bulky precatalyst for C-N bond formation

A very straightforward synthesis of [Pd(IPr*)(acac)Cl] has been developed from commercially available Pd(acac)2 and the easily prepared IPr*·HCl (acac = acetylacetonate; IPr* = N,N′-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene). The reactivity of the resulting complex [Pd(IPr*)(acac)Cl] (1) as a highly active PdII precatalyst for the Buchwald-Hartwig arylamination coupling has been explored. A wide range of substrates with varying electronic and steric demands of both coupling partners has been screened successfully. The chemoselectivity of the reaction was also explored by using aryl heterodihalides.