90331-54-7

Basic information

• Product Name: 2-Heptanol, 1-chloro-, methanesulfonate
• CAS NO: 90331-54-7
• Molecular Formula: C8H17ClO3S
• Mol File: 90331-54-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Heptanol, 1-chloro-, methanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Heptanol, 1-chloro-, methanesulfonate(90331-54-7)
• EPA Substance Registry System: 2-Heptanol, 1-chloro-, methanesulfonate(90331-54-7)

Safety Data

• Hazardous Substances Data: 90331-54-7(Hazardous Substances Data)

Upstream product

• 592-76-7 1-Heptene 
• 65411-49-6 tetrabutylammonium methanesulfonate 

Relevant articles and documents

PARTICIPATION OF SULFONATE IONS IN THE ELECTROPHILIC ADDITION OF HALOGENS TO OLEFINS

The reactions of ethylene, 1-heptene, cyclohexene, and styrene with chlorine and bromine in methylene chloride and chloroform in the presence of tetrabutylammonium p-toluenesulfonate and tetrabutylammonium methanesulfonate were investigated.In all cases the 2-halogenoalkyl esters of the sulfonic acids were obtained with comparable yields in addition to the 1,2-dihalides.The addition of chlorine and bromine to cyclohexene and also of bromine to 1-heptene in acetic acid in the presence of lithium p-nitrobenzenesulfonate leads to 2-halogenoalkyl esters of the sulfonicacids and acetic acid in addition to the 1,2-dihalides.These data indicate concurrent combination of the sulfonate anions at the concluding stage of AdE reactions.The mechanistic aspects and consequences of this effect are discussed.