90334-31-9Relevant academic research and scientific papers
1,4 asymmetric induction in the carbonyl reduction of a γ- ketosulfoxide
Solladie, Guy,Colobert, Francoise,Somny, Frederic
, p. 1227 - 1228 (2007/10/03)
A chiral sulfoxide induced high stereoselectivity in the DIBAL-H reduction of a methyl ketone located in the γ position as a result of a 1,4- asymmetric induction. Addition of a lanthanide triflate or cerium chloride completely reversed the stereoselectiv
Synthesis of Both Enantiomers of Optically Pure Saturated and α,β-Unsaturated γ-Substituted γ-Lactones from Chiral Sulphoxides. X-Ray Molecular structure of (3R,4S)-4-Methyl-4-t-butyl-3-(p-tolylthio)butanolide and of (3R,4R)-4-(Cyclohex-1-enyl)-4-methyl-3
Albinati, Alberto,Bravo, Pierfrancesco,Ganazzoli, Fabio,Resnati, Giuseppe,Viani, Fiorenza
, p. 1405 - 1416 (2007/10/02)
The lithium carbanions of optically pure (+)-(R)-p-tolyl alkyl sulphoxides (5) reacted with lithium bromoacetate and gave (+)-(R)-3-(p-tolylsulphinyl)carboxylic acids (3).Their dimetallation produced a chiral homoenolate dianion equivalent (6) which added
Chiral Homoenolate Anion Equivalents: Synthesis of Optically Pure 5-Substituted Furan-2(5H)-ones
Bravo, Pierfrancesco,Carrera, Paola,Resnati, Giuseppe,Ticozzi, Calimero
, p. 19 - 20 (2007/10/02)
Addition of the dianion of (+)-(R)-3-propionic acid (1) to aldehydes affords two main diastereoisomeric β-sulphinyl-γ-lactones, pyrolysis of which gives the two enantiomers of 5-substituted furan-2(5H)-ones in optically pure for
