903558-90-7

Upstream product

• 185996-36-5 (S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-butan-2-one 
• 1228116-11-7 C₁₉H₃₄O₃Si 
• 903558-89-4 4-(tert-butyl-diphenyl-silanyloxy)-3-methyl-butan-2-ol 

Downstream Products

• 1228116-05-9 C₁₃H₁₉IO₂ 
• 903558-93-0 (E)-(2R,3S,4S,6R,7R,10S)-2,7-Bis-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-11-(4-methoxy-benzyloxy)-4,6,8,10-tetramethyl-5-oxo-dodec-8-enoic acid tert-butyl ester 
• 903558-92-9 (E)-(2R,3S,4S,6R,7R,10S)-2-(tert-Butyl-dimethyl-silanyloxy)-7-hydroxy-3-methoxy-11-(4-methoxy-benzyloxy)-4,6,8,10-tetramethyl-5-oxo-dodec-8-enoic acid tert-butyl ester 
• 903558-91-8 (E)-(S)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-hex-2-enoic acid methyl ester 
• 903558-99-6 (E)-(S)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-hex-2-en-1-ol 
• 903558-88-3 (E)-(S)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-hex-2-enal 

Relevant academic research and scientific papers

Synthesis of a proposed structure for the diffusible extracellular factor of Xanthomonas campestris pv. campestris

A proposed structure for the diffusible extracellular factor (DF) of Xanthomonas campestris pv. campestris (Xcc) has been synthesized. Its MS spectrum and biological activity, however, contradict those of the natural product previously reported, suggesting that the structure for DF of Xcc must be reexamined.

Synthetic studies toward the total synthesis of tedanolide: assembly of the C1-C23 carbon backbone

A stereoselective assembly of the C1-C23 fragment representing the carbon backbone of tedanolide was accomplished utilizing a chiral boron reagent to effect the aldol coupling of the C1-C12 diketoester fragment with the C13-C23 aldehyde fragment.