903558-95-2

Upstream product

• 346708-27-8 (E)-(2R,3S,6R)-1-(tert-Butyl-dimethyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxy)-2-[(2S,4S,5R)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-4,6-dimethyl-hept-4-en-3-ol 
• 994-30-9 triethylsilyl chloride 
• 903558-94-1 (2S,4S,5R)-4-[(E)-(1S,2S,5R)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-2-triethylsilanyloxy-hex-3-enyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxane 

Downstream Products

• 903558-97-4 (6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol 
• 903558-96-3 (2S,4S,5R)-4-[(3E,6Z)-(1S,2S,5S)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-3,5-dimethyl-2-triethylsilanyloxy-octa-3,6-dienyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxane 
• 903558-87-2 (6E,9Z)-(2S,3R,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dienal 

Relevant academic research and scientific papers

Synthetic studies toward the total synthesis of tedanolide: assembly of the C1-C23 carbon backbone

A stereoselective assembly of the C1-C23 fragment representing the carbon backbone of tedanolide was accomplished utilizing a chiral boron reagent to effect the aldol coupling of the C1-C12 diketoester fragment with the C13-C23 aldehyde fragment.