90368-44-8

Upstream product

• 128-39-2 2,6-di-tert-butylphenol 
• 90388-37-7 N-(2,4-dichloro-6-oxo-2,4-cyclohexadien-1-ylidene)-4-nitrobenzamide 
• 96-76-4 2,4-di-tert-Butylphenol 
• 1139-52-2 4-bromo-2,6-di-tert-butylphenol 
• 127064-85-1 N-(2,4-dichloro-6-hydroxyphenyl)-N-(4-hydroxy-3,5-dimethoxyphenyl)-4-nitrobenzamide 
• 56962-03-9 2-amino-3,5-dichlorophenol 
• 127064-88-4 4-<<2,4-dichloro-6-<(4-nitrobenzoyl)oxy>phenyl>imino>-2,6-dimethoxy-2,5-cyclohexadien-1-one 
• 90368-43-7 4-Nitro-benzoic acid 2-amino-3,5-dichloro-phenyl ester 
• 732-26-3 2,4,6-tri-tert-butylphenoxol 

Downstream Products

• 90388-37-7 N-(2,4-dichloro-6-oxo-2,4-cyclohexadien-1-ylidene)-4-nitrobenzamide 
• 90368-45-9 (5,7-Dichloro-2-ethoxy-2,3-dihydro-benzo[1,4]oxazin-4-yl)-(4-nitro-phenyl)-methanone 
• 90368-46-0 (5,7-Dichloro-2,3,3a,9a-tetrahydro-benzo[b]furo[3,2-e][1,4]oxazin-4-yl)-(4-nitro-phenyl)-methanone 
• 90368-50-6 (5,7-Dichloro-2-diethylamino-3-methyl-benzo[1,4]oxazin-4-yl)-(4-nitro-phenyl)-methanone 
• 90368-55-1 (5,7-Dichloro-2-p-tolyl-2,3-dihydro-benzo[1,4]oxazin-4-yl)-(4-nitro-phenyl)-methanone 
• 90368-53-9 [5,7-Dichloro-2-(4-chloro-phenyl)-2,3-dihydro-benzo[1,4]oxazin-4-yl]-(4-nitro-phenyl)-methanone 
• 90368-54-0 [5,7-Dichloro-2-(3-chloro-phenyl)-2,3-dihydro-benzo[1,4]oxazin-4-yl]-(4-nitro-phenyl)-methanone 
• 90368-47-1 (7,9-Dichloro-4b,10a-dihydro-5,11-dioxa-10-aza-benzo[b]fluoren-10-yl)-(4-nitro-phenyl)-methanone 
• 90368-52-8 [5,7-Dichloro-2-(4-methoxy-phenyl)-2,3-dihydro-benzo[1,4]oxazin-4-yl]-(4-nitro-phenyl)-methanone 
• 90368-49-3 (9,11-Dichloro-6b,12a-dihydro-7-oxa-12-aza-benzo[k]fluoranthen-12-yl)-(4-nitro-phenyl)-methanone 
• 90368-48-2 (7,9-Dichloro-4a-morpholin-4-yl-1,2,3,4,4a,10a-hexahydro-phenoxazin-10-yl)-(4-nitro-phenyl)-methanone 

Relevant academic research and scientific papers

THE REACTIONS OF o-QUINONE MONOIMIDES WITH SOME THIOPHENES AND FURANS

o-Quinone monoimides undergo inverse electron demand Diels-Alder reactions with thiophene, 2-alkylated thiophenes, 2- and 2,5-alkylated furans and benzofurans. 2,5-Dimethylthiophenes and 2-methylbenzothiophene, on the other hand interact with o-quinone

The Reactions of an o-Quinone Monoimide with Some Phenols

The o-quinone monoimide N-(2,4-dichloro-6-oxo-2,4-cyclohexadien-1-ylidene)-4-nitrobenzamide (1) reacts with 2,6-dimethoxy-, 2,6-dimethyl-, and 2,6-dichlorophenols (2a-c) to form N-(2,4-dichloro-6-hydroxyphenyl)-N-(3,5-dimethoxy-, 3,5-dimethyl-, 3,5-dichloro-4-hydroxy)-4-nitrobenzamides (3a-c), respectively.Oxidation of 3a by 1 and 3b by DDQ lead to N-aryl-p-iminoquinones 4a,b.Oxidative dimerizations by either C-C or C-O coupling occur when 1 is admixed with the sterically hindered 2,6-di-tert-butyl-, 2,4-di-tert-butyl-, 4-bromo-2,6-di-tert-butyl-, and 2,4,6-tri-tert-butylphenols.

Synthesis and Reactions of N-(2,4-Dichloro-6-oxo-2,4-cyclohexadien-1-ylidene)-4-nitrobenzamide with Alkenes

The cycloaddition reactions of N-(2,4-dichloro-6-oxo-2,4-cyclohexadien-1-ylidene)-4-nitrobenzamide (3) and other o-quinone monoimides with electron-rich alkenes to give derivatives of 2,3-dihydro-4H-1,4-benzoxazine are described.Reaction of 3 with 2,3-dim