90369-00-9Relevant academic research and scientific papers
SYNTHESIS AND TRANSFORMATIONS OF METALLOCYCLES. 5. REGIOSELECTIVE SYNTHESIS OF β-SUBSTITUTED ALUMOCYCLOPENTANES BY THE CYCLOMETALLATION OF α-OLEFINS USING Et3Al IN THE PRESENCE OF Cp2ZrCl2
Dzhemilev, U. M.,Ibragimov, A. G.,Zolotarev, A. P.,Muslukhov, R. R.,Tolstokov, G. A.
, p. 2570 - 2578 (2007/10/02)
A new method has been proposed for the synthesis of N-, O-, and S-containing alumocyclopentanes by the reaction of Et3Al with functional α-olefins in the presence of catalytic amounts of Cp2ZrCl2.The alumocyclopentanes obtained may react with S8 to give β-substituted tetrahydrothiophenes.
