90381-81-0Relevant academic research and scientific papers
Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate: A mild and efficient oxidant for oxidation of thiols, sulfides and aromatic amines to the corresponding disulfides, sulfoxides and azo compounds
Hajipour,Mohammadpoor Baltork,Kianfar
, p. 607 - 610 (2007/10/03)
Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate (BAABCPS) 1, readily prepared as orange solid from commercially available 1,4-diazabicyclo[2.2.2]octane (DABCO) and potassium peroxodisulfate converts thiols, sulfoxides and aromatic amines to the corresponding disulfides, sulfoxides and azo compounds respectively.
1-Benzyl-1-aza-4-azoniabicyclooctane periodate as new oxidant for oxidation of thiols and sulfides to the corresponding disulfides and sulfoxides under anhydrous conditions
Hajipour, A. R.,Mahboubghah, N.
, p. 1041 - 1043 (2007/10/03)
1-Benzyl-1-aza-4-azoniabicyclooctane periodate (BAABCOP) 1, readily prepared as an orange solid from commercially available DABCO (1,4-diazobicyclooctane) performs oxidation in anhydrous conditions. Under these conditions, thiols are selectively oxidised to disulfides. Sulfides are also oxidised to the corresponding sulfoxides under these conditions.
Solid state oxidation of aromatic sulfides to corresponding phenyl and p-tolyl sulfoxides and sulone using oxone
Hajipour, A. R.
, p. 1069 - 1070 (2007/10/03)
Phenyl and p-tolyl sulfides 1 can be selectively oxidised to the corresponding sulfoxides 2 or sulfones 3 in solid state condition using oxone. The advantages of this method are the use of cheap and safe reagents, high yield and simple operating conditions.
