90397-88-9Relevant academic research and scientific papers
REGIOSELECTIVE RING OPENING OF UNSYMMETRICAL CYCLIC ETHERS WITH THE AlCl3-NaI-ACETONITRILE SYSTEM: APPLICATION TO HYDROXYLATION OF ent-KAURENE.
Node, Manabu,Kajimoto, Tetsuya,Nishide, Kiyoharu,Fujita, Eiichi,Fuji, Kaoru
, p. 219 - 222 (2007/10/02)
Unsymmetrically substituted 5-membered cyclic ethers were effectively cleaved with the AlCl3-NaI-CH3CN system at the less hindered carbon atom to afford δ-iodoalcohols.Conversion of ent-kaurene to ent-14α- and ent-12β-hydroxykaurene was achieved through t
