90454-51-6

Basic information

• Product Name: N-phenoxycarbonyl-(2,3,4,5-tetrachloro-1-thiophenio)amide
• Synonyms: N-phenoxycarbonyl-(2,3,4,5-tetrachloro-1-thiophenio)amide
• CAS NO: 90454-51-6
• Molecular Weight: 357.044
• Mol File: 90454-51-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-phenoxycarbonyl-(2,3,4,5-tetrachloro-1-thiophenio)amide(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenoxycarbonyl-(2,3,4,5-tetrachloro-1-thiophenio)amide(90454-51-6)
• EPA Substance Registry System: N-phenoxycarbonyl-(2,3,4,5-tetrachloro-1-thiophenio)amide(90454-51-6)

Safety Data

• Hazardous Substances Data: 90454-51-6(Hazardous Substances Data)

Upstream product

• 6012-97-1 2,3,4,5-tetrachlorothiophene 
• 17667-39-9 phenyl carbonazidate 

Downstream Products

• 6012-97-1 2,3,4,5-tetrachlorothiophene 
• 59-49-4 2-Benzoxazolinone 
• 100100-93-4 5,6,7,8-Tetrachlor-1,2,3,4,4a,8a-hexahydro-1,4-methanonaphtalin 
• 105752-80-5 C₁₂H₁₃NO₂S 
• 105752-79-2 4-Methyl-3,6-dihydro-[1,2]thiazine-2-carboxylic acid phenyl ester 
• 105780-92-5 5-Methyl-3,6-dihydro-[1,2]thiazine-2-carboxylic acid phenyl ester 
• 95308-73-9 C₁₃H₁₅NO₂S 
• 72524-27-7 5,6,7,8-Tetrachloro-1,2,3,4,4a,8a-hexahydro-naphthalene 
• 95308-69-3 C₁₃H₁₅NO₂S 
• 95308-70-6 4,5-Dimethyl-3,6-dihydro-[1,2]thiazine-2-carboxylic acid phenyl ester 

Relevant articles and documents

Thiophene S,N-Ylides: A New Versatile Class of Sulphimides

Tetrachlorothiophene reacts with methyl, ethyl, and phenyl azidoformates and with toluene-p-sulphonyl azide at 130-150 deg C to give stable thiophene S,N-ylides. 2,5-Dichloro and 2,5-dibromo-thiophene and tetrabromothiophene yield products derived by nitrene attack at the α-position.The S,N-ylides undergo ready photolysis to liberate the parent nitrene, and react with a wide variety of electron-rich dienophiles as 4?-components to give tetrachlorodihydrobenzenes with extrusion of a thionitroso compound.With dienes the ylides react either as 2?- or 4?-systems.Thus with anthracene a dihydrothiophene analogue of triptycene is generated efficiently aromatised and de-ylidated with zinc in methanol.With dimethyl acetylenedicarboxylate the ylides yield a thiazocine by a novel ring expansion.Oxidation of the ylide system with 3-chloroperbenzoic acid gives the corresponding ylide S-oxide.Tetrachlorothiophene also reacts efficiently with diazoalkanes under rhodium acetate catalysis to give thiophene S,C-ylides, which undergo cycloaddition with nucleophilic alkenes much more slowly than their nitrogen analogues.