90464-82-7Relevant academic research and scientific papers
Miscellaneous reactions of some tris(trimethylsilyl)methylsilicon compounds
Eaborn, Colin,Fattah, Faraedan A.
, p. 1 - 8 (1990)
TsiSiMe2I (Tsi = (Me3Si)3C) gives TsiSiMe2OMe on treatment with AgBF4 in MeOH but some TsiSiMe2F if an excess of CsF is also present.The triflates TsiSiMe2OSO2CF3 and (Me3Si)2C(SiMePh2)(SiMe2OSO2CF3) react with alkali metal salts MX to give the correspond
An SN2 (Intermediate) Mechanism for Solvolysis of Organosilicon Iodides ?
Al-Shali, Saman A. I.,Eaborn, Colin,Fattah, Faraedon A.,Najim, Sabah T.
, p. 318 - 319 (2007/10/02)
The hydrolysis (in H2O-MeCN or H2O-Me2SO) and methanolysis of TsiSiR2I give only unrearranged products TsiSiR2Y (Y = OH or OMe); thus the methanolyses of TsiSiMe2I and TsiSiPhHI seem likely to be SN2(intermediate
