904672-47-5

Basic information

• Product Name: 1-(4-fluorophenyl)but-3-en-1-one oxime
• Synonyms: 1-(4-fluorophenyl)but-3-en-1-one oxime
• CAS NO: 904672-47-5
• Molecular Weight: 179.194
• Mol File: 904672-47-5.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 1-(4-fluorophenyl)but-3-en-1-one oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-fluorophenyl)but-3-en-1-one oxime(904672-47-5)
• EPA Substance Registry System: 1-(4-fluorophenyl)but-3-en-1-one oxime(904672-47-5)

Safety Data

• Hazardous Substances Data: 904672-47-5(Hazardous Substances Data)

Upstream product

• 86718-78-7 1-(4-fluorophenyl)-3-buten-1-ol 
• 459-57-4 4-fluorobenzaldehyde 

Downstream Products

• 1160472-60-5 3-(4-fluorophenyl)-4,5-dihydroisoxazole-5-carbonitrile 
• 867203-96-1 3-(4-fluorophenyl)-5-iodomethylisoxazoline 
• 833462-37-6 3-(4-fluorophenyl)-5-[(phenylselanyl)methyl]-4,5-dihydroisoxazole 
• 472976-35-5 3-p-fluorophenyl-5-hydroxymethyl-Δ²-isoxazoline 
• 253443-43-5 5-(chloromethyl)-3-(4-fluorophenyl)-4,5-dihydroisoxazole 
• 491875-99-1 3-(4-fluoro-phenyl)-5-methylisoxazole 
• 1616603-22-5 C₁₂H₁₂FNO₂ 
• 110319-94-3 2-(4-fluorophenyl)-1H-pyrrole 
• 472976-39-9 C₁₀H₉FN₄O 

Relevant articles and documents

Visible Light-Promoted Recyclable Carbon Nitride-Catalyzed Dioxygenation of β,γ-Unsaturated Oximes

A visible-light-induced dioxygenation of β,γ-unsaturated oximes for the synthesis of diverse useful isoxazolines bearing a hydroxyl moiety was developed by employing graphitic carbon nitride (g-C3N4) as a heterogeneous photocatalyst under an air atmosphere. Noted that, the eminent advantages of this metal-free protocol include step economy, easy operation, a recyclable photocatalyst, external reductant-/oxidant-free and mild reaction conditions. Additionally, mechanistic studies indicated hydroxyl radical was generated under the photocatalysis of g-C3N4.

Electrochemical Chalcogenation of β,γ-Unsaturated Amides and Oximes to Corresponding Oxazolines and Isoxazolines

The current report represents a transition-metal-free synthesis of oxazoline and isoxazoline derivatives by a tandem electro-oxidative chalcogenation-cyclization process. Both C?Se and C?S bond-forming protocols were developed without using any external oxidant and the reaction was performed at room temperature, open to the air. Using this methodology, 29 substituted oxazoline and 16 substituted isoxazoline derivatives were synthesized with up to 91% isolated yield. (Figure presented.).

Green organocatalytic synthesis of isoxazolines via a one-pot oxidation of allyloximes

A green, sustainable, organocatalytic, and efficient synthesis of isoxazolines from allyloximes was developed. A 2,2,2-trifluoroacetophenone-catalyzed oxidation of allyloximes, utilizing H2O2 as the green oxidant, was taken advantage of in order to introduce a cheap and environmentally friendly protocol for the synthesis of substituted isoxazolines. A variety of substitution patterns, both aromatic and aliphatic moieties, are well tolerated, leading to isoxazolines in moderate to excellent yields.