90493-77-9Relevant academic research and scientific papers
THE STUDY OF INTRAMOLECULAR FREE RADICAL CYCLIZATION OF α-SULFENYL RADICAL
Tsai, Yeun-Min,Chang, Fu-Chang,Huang, Jimin,Shiu, Chi-Lung
, p. 2121 - 2124 (2007/10/02)
α-Sulfenyl radical can be generated from α-chlorosulfide or dithioacetal.The olefin substituent effect on the intramolecular radical cyclization of this type was studied.
A HIGHLY REGIO- AND STEREOSELECTIVE SYNTHESIS OF INTERNAL OLEFINS VIA AN ELIMINATION OF TRIMETHYLSTANNYL GROUP
Murayama, Eigoro,Uematsu, Masahiro,Nishio, Hiroyuki,Sato, Tadashi
, p. 313 - 316 (2007/10/02)
Internal reaction of secondary alkyltin(IV) compounds having thionium ion gave internal trans olefins with high yield and regio- and stereoselectivity via 1,5- or 1,6-transfer of a hydride β to the trialkylstannyl group.
