90536-09-7Relevant academic research and scientific papers
Zinc-mediated alkylation and acylation of 1,3-dicarbonyl compounds
Yadav,Reddy, B. V. Subba,Mishra, Anand Kumar
experimental part, p. 280 - 281 (2010/09/05)
1,3-Dicarbonyl compounds undergo smooth allylation, benzylation, propargylation, and acylation with halides using metallic zinc in DMF at 60 °C to afford the corresponding allyl, benzyl, 2-propynyl, and acylated 1,3-diesters in good yields. In the case of cyclic 1,3-diketones, the corresponding enol ethers are obtained as sole products instead of C-alkylation.
Radical cyclization of α-iodo enones by photoinduced electron transfer reaction
Sha, Chin-Kang,Santhosh,Tseng, Chen-Tso,Lin, Chien-Ting
, p. 397 - 398 (2007/10/03)
A facile intramolecular radical cyclization of α-iodo enones effected by triethylamine-mediated photoinduced electron transfer (PET) reactions is described.
